Use of conditioning time to investigate the mechanisms of interactions of selected fatty acids on hematite Part II laboratory investigations

It is the aim of this paper to examine the effects of conditioning time on the flotation of hematite using three technical grade fatty acid reagents as providing additional evidence on their mechanism of interaction with the hematite surface. Various mechanisms have been postulated as occurring as conditioning time is increased. Both physical (e.g. conditioning time and power input) and chemical (nature, dispersion and solubility of the adsorbing species) contribute to the mechanisms of attachment of collector. In this paper, the mechanism of attachment of oleate to hematite can be readily explained by chemisorption, but the mechanism of attachment of lauric acid appears to be physical adsorption at neutral pH. The flotation of hematite with a mixture of tallow-type fatty acids (palmitic, stearic and oleic acids) is very sensitive to conditioning time, and suggests that, even though flotation is very effective at short conditioning times, it is very susceptible to the presence of fines and their associated high surface areas. It is therefore obvious that both the physical and chemical conditions contribute to the mechanisms of adsorption of fatty acids on iron-containing oxide minerals and must be understood in order to optimise the flotation of these minerals in an industrial situation.     

A dinuclear copper(II) complex and a zigzag chain iron(II) polymer based on the 4-antipyrine derived Schiff base ligands: The hydroxylation and redox occurred under the solvothermal conditions

A new dinuclear copper(II) compound, [Cu₂(L1-O)₂] (1) (L1 = (4E)-4-(2-hydroxybenzylideneamino)-1,2-dihydro-2,3-dimethyl-1-phenylpyrazol-5-one), and zigzag chain polymer, {[FeCl₂(L2)]}_n (2) (L2 = 1,5-dimethyl-2-phenyl-4-{[(1E)-pyridine-4-ylmethylene]amino}-1,2-dihydro-3H-pyrazol-3-one), were synthesized by solvothermal reactions and structurally characterized. The methyl group hydroxylation and the redox have been observed in the preparation of 1 and 2, respectively.     

Evaluation method of cracking resistance of lightweight aggregate concrete

The cracking behavior of lightweight aggregate concrete（LWAC） was investigated by mechanical analysis, SEM and cracking-resistant test where a shrinkage-restrained ring with a clapboard was used. The relationship between the ceramsite type and the cracking resistance of LWAC was built up and compared with that of normal-weight coarse aggregate concrete（NWAC）. A new method was proposed to evaluate the cracking resistance of concrete, where the concepts of cracking coefficient ζt（t） and the evaluation index Acr（t） were proposed, and the development of micro-cracks and damage accumulation were recognized. For the concrete with an ascending cracking coefficient curve, the larger Acr（t） is, the lower cracking resistance of concrete is. For the concrete with a descending cracking coefficient curve, the larger Acr（t） is, the stronger the cracking resistance of concrete is. The evaluation results show that in the case of that all the three types of coarse aggregates in concrete are pre-soaked for 24 h, NWAC has the lowest cracking resistance, followed by the LWAC with lower water absorption capacity ceramsite and the LWAC with higher water absorption capacity ceramsite has the strongest cracking resistance. The proposed method has obvious advantages over the cracking age method, because it can evaluate the cracking behavior of concrete even if the concrete has not an observable crack.     

Self-Adhesive Polydimethylsiloxane Foam Materials Decorated with MXene/Cellulose Nanofiber Interconnected Network for Versatile Functionalities

Polydimethylsiloxanes (PDMS) foam as one of next-generation polymer foam materials shows poor surface adhesion and limited functionality, which greatly restricts its potential applications. Fabrication of advanced PDMS foam materials with multiple functionalities remains a critical challenge. In this study, unprecedented self-adhesive PDMS foam materials are reported with worm-like rough structure and reactive groups for fabricating multifunctional PDMS foam nanocomposites decorated with MXene/cellulose nanofiber (MXene/CNF) interconnected network by a facile silicone foaming and dip-coating strategy followed by silane surface modification. Interestingly, such self-adhesive PDMS foam produces strong interfacial adhesion with the hybrid MXene/CNF nano-coatings. Consequently, the optimized PDMS foam nanocomposites have excellent surface super-hydrophobicity (water contact angle of ≈159^o), tunable electrical conductivity (from 10⁻⁸ to 10 S m⁻¹), stable compressive cyclic reliability in both wide-temperature range (from −20 to 200 ^oC) and complex environments (acid, sodium, and alkali conditions), outstanding flame resistance (LOI value of >27% and low smoke production rate), good thermal insulating performance and reliable strain sensing in various stress modes and complex environmental conditions. It provides a new route for the rational design and development of advanced PDMS foam nanocomposites with versatile multifunctionalities for various promising applications such as intelligent healthcare monitoring and fire-safe thermal insulation.     

Hyperelastic,Robust, Fire-Safe Multifunctional MXene Aerogels with Unprecedented Electromagnetic Interference Shielding Efficiency

MXene aerogels have shown great potential for many important functional applications, in particular electromagnetic interference (EMI) shielding. However, it has been a grand challenge to create mechanically hyperelastic, air-stable, and durable MXene aerogels for enabling effective EMI protection at low concentrations due to the difficulties in achieving tailorable porous structures, excellent mechanical elasticity, and desired antioxidation capabilities of MXene in air. Here, a facile strategy for fabricating MXene composite aerogels by co-assembling MXene and cellulose nanofibers during freeze-drying followed by surface encapsulation with fire-retardant thermoplastic polyurethane (TPU) is reported. Because of the maximum utilization of pore structures of MXene, and conductive loss enhanced by multiple internal reflections, as-prepared aerogel with 3.14 wt% of MXene exhibits an exceptionally high EMI shielding effectiveness of 93.5 dB, and an ultra-high MXene utilization efficiency of 2977.71 dB g g⁻¹, tripling the values in previous works. Owing to the presence of multiple hydrogen bonding and the TPU elastomer, the aerogel exhibits a hyperelastic feature with additional strength, excellent stability, superior durability, and high fire safety. This study provides a facile strategy for creating multifunctional aerogels with great potential for applications in EMI protection, wearable devices, thermal management, pressure sensing, and intelligent fire monitoring.     

A heterogeneous multi-attribute case retrieval method based on neutrosophic sets and TODIM for emergency situations

Applied Intelligence - Heterogeneous multi-attribute case retrieval is a crucial step in generating emergency alternatives during the course of emergency decision making (EDM) by referring to...     

基于改进BiGRU-CNN的中文文本分类方法

传统的自注意力机制可以在保留原始特征的基础上突出文本的关键特征,得到更准确的文本特征向量表示,但忽视了输入序列中各位置的文本向量对输出结果的贡献度不同,导致在权重分配上存在偏离实际的情况,而双向门控循环单元（BiGRU）网络在对全局信息的捕捉上具有优势,但未考虑到文本间存在的局部依赖关系。针对上述问题,提出一种基于改进自注意力机制的BiGRU和多通道卷积神经网络（CNN）文本分类模型SAttBiGRU-MCNN。通过BiGRU对文本序列的全局信息进行捕捉,得到文本的上下文语义信息,利用优化的多通道CNN提取局部特征,弥补BiGRU忽视局部特征的不足,在此基础上对传统的自注意力机制进行改进,引入位置权重参数,根据文本向量训练的位置,对计算得到的自注意力权重概率值进行重新分配,并采用softmax得到样本标签的分类结果。在两个标准数据集上的实验结果表明,该模型准确率分别达到98.95%和88.1%,相比FastText、CNN、RCNN等分类模型,最高提升了8.99、7.31个百分点,同时精确率、召回率和F1值都有较好表现,取得了更好的文本分类效果。     

基于Seam Carving的图像放大算法研究与改进

针对Seam Carving图像放大算法中,能量值前k小的像素带可能出现共用点的情况,提出了一种改进的图像放大自适应算法,通过判断图像中出现共用点的像素带的情况及计算其共用率的值,经过一定的策略确定待新增的像素带位置,该算法使得图像中视觉关注非重要信息区域像素带的增加能得到较均匀的分布;实现了人工干预选择视觉关注重要区域的方法,避免了自适应算法本身因误判视觉关注重要区域而带来关注对象发生变形扭曲的情况.实验证明,改进的算法能得到更好的放大效果.     

A Reducing Saturation Method for DMSP/OLS Nighttime Light Image Combining Landsat Data

Defense Meteorological Satellite Program/Operational Linescan System(DMSP/OLS)is one of the data sources,which can effectively reflect human activities of earth surfaces.During the past decade,DMSP/OLS had been extensively applied in urban extraction and extension study.In the recent year,the Vegetation Adjusted NTL Urban Index(VANUI)has been proposed and had proven to be a simple,convenient and high precision desaturation index to extract urban area.In VANUI method,negative values of imagery were directly eliminated to remove water body,which not only removed the bridge over the river and building but also extracted the aquaculture areas along the coast,thus,this method reduced the extraction accuracy.This paper proposed a new index\|RwNTLI,combining DMSP/OLS nighttime light data and the vegetation index (NDVI)and water index (MNDWI)which were constructed by Landsat data.In this study,Guangzhou was taken as experimental area.By comparing the VANUI index with the ability to identify ground objects as well as the ability to alleviate saturation regions,the result showed RwNTLI index could effectively solve the problem of VANUI as well as eliminate saturation effect of nighttime light imagery.Among them,the correlation between RwNTLI index and RCNTL is better than that of VANUI index and RCNTL.Therefore,RwNTLI index is a simple and effective index of luminous desaturation,which has more advantages than VANUI index in describing the characteristics of night lights of urban areas and will have higher application value in urban built\|up areas in the future.     

IBI and CA Model based Extraction of Urban Built\|up Areaand Its Application：A Case Study in Shanghai

At present,the automatic extraction of urban built\|up area is still a problem.Taking Shanghai city as an example,this research uses the binary image,which was derived from an IBI(index\|based built\|up index)image,as the geographical cellular automaton initial input data.This was then imported to the extended cellular automata model for further processing.After a series of processing such as thresholding,corrosion and connectivity test,the urban built\|up area was simulated and can be extracted.Based on this method,the urban built\|up area of Shanghai in five different years between 1987 and 2015 was extracted using multi\|temporal Landsat images of Shanghai.In addition,the urban growth intensity index,the concentric buffers analysis and radar chart analysis were calculated and used to analysis spatiotemporal pattern of Shanghai urban expansion in the 28 study years.The result shows that the built\|up area of Shanghai was expanded from 195 km² in 1987 to 1759 km² in 2015,which is eight times as large as that in 1987.In the period between 1987 and 2002,the urban built\|up area expanded mainly along the North\|South axis of the Huangpu River.However,after 2002 the expansion rate was increased more quickly,and the direction of the expansion was shifted to an east to west direction.Generally speaking,Shanghai has experienced a rapid urban expansion in the recent three decades.